Recently, the scientists from the Institute of Modern Physics (IMP), Chinese Academy of Sciences (CAS) and the Advanced Energy Science and Technology Guangdong Laboratory have fabricated high-temperature-resistant polyethylene terephthalate (PET) separators for lithium-ion batteries. The related results were published in ACS Applied Materials & Interfaces.

The separator, as a key part of the lithium-ion batteries, plays a crucial role in ensuring battery safety, for it can insulate the cathode and anode to avoid short-circuiting, and it can provide transport paths for lithium ions.

In previous studies, researchers improved the performance of polyolefin separators by coating them with inorganic or organic materials. However, these methods cannot fundamentally improve the thermal stability of separators. Therefore, developing new lithium-ion battery separators with high-temperature resistance is of great importance to enhance the safety of lithium-ion batteries.

Innovatively combining heavy ion irradiation and chemical etching technologies, scientists have developed PET-based separators with high-temperature resistance. Compared with commercial polyolefin separators, the PET-based separators possess nanochannels with uniform channel size and distribution, and demonstrate not only high electrolyte wettability but also exceptional thermal stability, capable of withstanding temperatures as high as 180 °C.

Moreover, the test results showed that the PET-based separator exhibits good cycle performance at both room and high temperature, with a high lithium-ion transfer number of 0.59.

This new study applies heavy ion irradiation technology to the field of new energy, and provides a competitive approach for producing thermotolerant separators.

DOI: https://doi.org/10.1021/acsami.3c13519

Figure. The SEM image and high-temperature cycle performance of the PET-based separator. (Image by IMP)